Dinuclear Rhombic Copper(I) Iodide Complexes with Rigid Bidentate Arsenic Ligands
نویسندگان
چکیده
We have recently developed a series of arsenic ligands based on practical synthetic strategies. Herein, three kinds bidentate with rigid linkers were selected to construct dinuclear rhombic copper(I) iodide (CuI) complexes, whose structures analyzed by X-ray crystallography. They had sufficient solubility in organic solvents, and it was confirmed that their coordination forms kept the solutions. Intense solid-state emissions observed even at room temperature, emission colors varied from yellow red ligands. utilizing routes. luminescent CuI complexes. The In addition, complexes an solvent, properties robust against external stimuli such as grinding cooling.
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The aim of the present study is to synthesize the oxovanadium complex of the V3+ ion with isatin sciff bases. Spectroscopic methods have been used to confirm these models of complexation and to understand the structures of the species formed in methanolic solution. We also have isolated a complex of Vanadium (III) with isatin schiff bases in the solid phase.
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ژورنال
عنوان ژورنال: Chemistry Letters
سال: 2021
ISSN: ['0366-7022', '1348-0715']
DOI: https://doi.org/10.1246/cl.200763